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Obtención y caracterización de un bioplástico a partir de garbanzo (cicer arietinum)

Obtaining and characterizing a bioplastic from chickpea (cicer arietinum)

^1<= /o:p>	Jonathan Alexander Barrera Pilataxi = https://orcid.org/0000-0001-5= 656-6693Escuela Superior Politécnica de Chimborazo, Facultad de Ciencias. Riobamba, Ecuad= or alexander.barrera@espo= ch.edu.ec	<= /b>
^= 2	Luis Santiago Carrera Almendáriz <= /span>https://orcid.org/0000-0002-3262-5895 Escuela Superior Politécnica de Chimborazo, Facultad de Ciencias. Riobamba, Ecuador luissantiago.carrera@espoc= h.edu.ec
^= 3	Ana Gabriela Flores-Huilcapi = https://orcid.org/0000-0001-8748-7859 Escuela Superior Politécnica de Chimborazo, Orellana, Ecuador ana.flores@espoch.edu.ec	&n= bsp;
^= 4	Adrián Alejando Rodríguez Pinos = https://orcid.org/0000-0002-7157-1877 Escuela Superior Politécnica de Chimborazo, Facultad de Ciencias. Riobamba, Ecuad= or adrian.rodriguez@espoch.edu.ec	&n= bsp;

=	Artículo de Investigac= ión Científica y Tecnológica Enviado: 09/11/2021 Revisado: 24/11/2021 Aceptado: 21/12/2021 Publicado:05/01/2022 DOI: https://doi.org/10.33262/concienciadigital= .v5i1.1964
<= /u>
Cítese:		Barrera Pilataxi, J.= A., Carrera Almendáriz= , L. S., Flores Huilcapi, A. G., & Rodríguez Pinos, A. A. (2022). Obtención y caracterización de un bioplástico a partir de garbanzo (cicer arietinum) . ConcienciaDigital, 5(1), 57-69. https://doi.org/10.33262/concienciadigital.v5i1.1964 &nb= sp;
		CONCIENCIA DIGITAL, es una Revista Multidisciplinar, Trimestral, que se publicará en soporte electrónico tiene como misión contribuir a la formació= n de profesionales competentes con visión humaní= stica y crítica que sean capaces de exponer sus resultados investigativos y científicos en la misma medida que se promueva mediante = su intervención cambios positivos en la sociedad. <= span style=3D'mso-bookmark:_Hlk93071979'>https://concienciadigital.org <= /span> <= span style=3D'mso-bookmark:_Hlk93071979'>La rev= ista es editada por la Editorial Ciencia Digital (Editorial de prestigio registrada en la Cámara Ecuatoriana de Libro con No de Afiliación 663) www.celibro.org.ec &= nbsp;
		Esta revista está protegida bajo una licencia Creative Commons AttributionNonCommercialNoDerivatives 4.0 International. Copia de la licencia: http://creativecommons.org/li= censes/by-nc-nd/4.0/
Palab= ras claves: almidón, amilosa, amilopectina, bioplástico, garbanzo.		Resumen Intro= ducción: El plástico (polietileno) es un aliado importante en la cotidianidad del ser humano, sin embargo, su uso y excesiva acumulación ha generado una grave problemática ambiental. Obj= etivo: Esta investigación busca desarrollar un material biodegradable a partir d= el del almidón de garbanzo con características similares al plástico y que potencialmente se pueda usar como recubrimiento para alimentos. Metodo= logía: Se realizó una revisión bibliográfica para determinar el método de extrac= ción del almidón de garbanzo, seleccionando el método de vía húmeda. Se realiz= a un diseńo experimental 22 de dos factores que son peso de almidón (g) y volu= men de agua destilada (mL) y a cada tratamiento se adiciona 1,5 mL de glicerina (plastificante) = y 4 mL de ácido acético (modificador químico). Se ensay= an las propiedades mecánicas de los bioplásticos bajo la Norma NTE INEN 2635:2012 Métodos de ensayo para las propiedades de tracción de láminas delgadas y = su biodegradabilidad bajo la Norma Técnica INEN 2643:2012. Especificaciones para plásticos compostables. Resultados: Se caracterizó el almidón mediante pruebas fisicoquímicas: resultando 19% de amilosa, 81% de amilopectina, 4,53 de pH, 39249 mPas de visco= sidad, 60şC de temperatura de gelatinización y 4,82 de índice de solubilidad. La formulación del bioplástico con mejores propiedades mecánicas está consti= tuida por: 3,5 % (1,5 mL) de glicerina, 9,5 % (4 mL) de ácido acético, 3,5 % (1,5 g) de almidón de garbanzo y 83,5 % (35 mL) de agua destilada. = El biopolímero seleccionado presenta alta biodegradabilidad acuosa y características físicas: 4,9 Mpa de módulo de elasticidad, 24,2 % de elongación, 2,8 N de carga máxima, 1 Mpa de esfuerzo máximo. Conclusión: El bioplástico obtenido a partir del almidón de garbanzo presenta propiedades mecánicas comparables con las láminas de polietileno de baja densidad y propiedades biodegradables que permiten us= arlo en envoltura para alimentos.
Keywords:		Abstract Introduction: Plastic (polyethylene) is an important ally in the daily life of human beings; however, its use and excessive accumulati= on has generated a serious environmental problem. Objective: This research seeks to develop a biodegradable material based on chickpea star= ch with characteristics like plastic that can potentially be used as a coati= ng for food. Methodology<= span style=3D'mso-bookmark:_Hlk93071979'>: A literature review was carried out to determine the extraction method of chickpea starch, selecting the wet method. A two-factor experimental desi= gn with two factors, starch weight (g) and volume of distilled water (mL), was carried out and 1.5 mL of glycerin (plasticizer) and 4 mL of acetic acid (chemical modifier) were added to each treatment. The mechanical properti= es of bioplastics are tested under NTE INEN 2635:2012 Test methods for tensi= le properties of thin films and their biodegradability under Technical Stand= ard INEN 2643:2012. Specifications for compostable plastics. Results: The starch was characterized by physicochemical tests: 19% amylose, 81% amylopectin, 4.53 pH, 39249 mPas viscosity, 6= 0şC gelatinization temperature and 4.82 solubility index. The bioplastic formulation with better mechanical properties is constituted by: 3.5 % (1= .5 mL) glycerin, 9.5 % (4 mL) acetic acid, 3.5 % (1.5 g) chickpea starch and 83.5 % (35 mL) distilled water. The selected biopolymer presents high aqu= eous biodegradability and physical characteristics: 4.9 M= pa modulus of elasticity, 24.2 % elongation, 2.8 N maximum load, 1 Mpa maximum stress. Conclusion: The bioplastic obtained from chickpea starch presents mechanical properties comparable to low density polyethylene films and biodegradable properties that allow its use in food wrapping.

Introducción

El mundo hoy en día enfrenta graves problemas por el consumo y producción excesivo de plásticos de origen petroquímico, tal es el caso de Ecuador que según datos proporcionados por el Instituto Nacional de Estadísticas y Censos (INEC, 2018) los ecuatorianos produjeron 12.739,01 toneladas de basura diarias, de este total de basura el 11,43% era plástico= , es decir se produjeron 531.461 toneladas anuales de este material (López et al= ., 2014; Xu & Yang, 2012; Tian & Bilal, 2019).

En los últimos ańos las investigaciones se han centrado en buscar alternativas viables para la suplantación del plástico común, en esta búsqu= eda los recursos renovables han sido la mejor opción para la extracción del alm= idón como componente principal para la formulación del bioplástico (Sawpan et al., 2009; Alexandre et al., 2016). Por ell= o se ha evaluado diferentes productos en la mayoría tubérculos como la papa, cam= ote y yuca, estos productos juegan un papel importante en la contribución globa= l de nutrición y energía a las personas en los países en desarrollo (Adilah et al., 2018; Herrera et al., 2014; Fonseca-Ga= rcía et al., 2021). Los bioplásticos han estado en el foco de los esfuerzos de investigación y desarrollo académicos e industriales durante más de dos décadas. Su producción mundial alcanzó los 4 millones de toneladas métricas= en 2015 y sigue aumentando considerablemente (Xu & Yang, 2012; Romero & Zhang, 2019). El sólido crecimiento de este campo emergente de la industria está impulsado por múltiples factores, incluida la conciencia ambiental y l= as preferencias cambiantes de los consumidores, nuevas políticas y legislación, así como el desarrollo de producto (Imre et al.= , 2019; Hu, 2014; Jőgi & Bhat, 2020; Li et al., 2020). Los bioplásticos, por definición, son biodegradable= s y / o se obtienen de fuentes renovables ofreciendo una alternativa sostenible= a los plásticos convencionales. Se valora que la capacidad de producción de bioplásticos tenderá a aumentar hasta 2,4 millones de toneladas para 2023. = Los principales impulsores de este crecimiento son los biopolímeros innovadores como PHA (polihidroxialcanoatos) y PLA (ácido poliláctico) (Astuti & Erprihana, 2014; Park et al., 2020; Hu, 2014; Tian & Bilal, 2019).=

Metodología

Esta investigación es de tipo experimental. Se seleccionó un método de obtención de almidón de garbanzo por vía húmeda (Alexan= dre et al., 2016). Se caracterizó el almidón obtenido para determinar porcentaje de amilosa y amilopectina (Li et = al., 2020). Se desarrolló un diseńo experimental para formular el bioplástico. Con base= a las distintas formulaciones se evaluó su biodegradabilidad y sus propiedades mecánicas.

Tabla 1=

Diseńo para la obtención de almidón para 100 g de garbanzo y 300 mL de agua destil= ada

TRATAMIENTOS	Repeticiones	Tiempo de trituración (s)
T1	R1	15
R2	15
R3	15
R4	15
R5	15
R6	15
T2	R1	30
R2	30
R3	30
R4	30
R5	30
R6	30

Tabla 1

Diseńo para la obtención de almidón para 100 g de garbanzo y 300 mL de agua destilada (continuación)

TRATAMIENTOS	Repeticiones	Tiempo de trituración (s)
T3	R1	45
R2	45
R3	45
R4	45
R5	45
R6	45
T4	R1	60
R2	60
R3	60
R4	60
R5	60
R6	60

Fuente:= Elaboración propia

Se planteó un diseńo de experimentos para la obtención de almidón por vía húmeda con 6 repeticiones por cada tratamiento, donde el factor variabl= e es el tiempo de trituración, manteniendo constante la cantidad de garbanzo (g)= y volumen de agua destilada (mL), según tabla 1.

Para la formulación se utiliza plastificantes como: glicerina y ácido acético en una proporción fija de 1,5 mL/4 mL. Se prueba variando la propor= ción de almidón y agua destilada como se muestra en la tabla 2.

Tabla 2

Formulación para la obtención del bioplástico de garbanzo

FORMULACIÓN	ALMIDÓN (g)	AGUA DESTILADA (mL)
A1	1,5	30
A2	1,5	35
A3	2	30
A4	2	35

Fuente:= Elaboración propia

Se evaluó las propiedades mecánicas del bioplástico obtenido y el porcentaje de humedad, elongación y flexibilidad de los bioplásticos desarrollados.

Resultados

La extracción del almidón por vía húmeda se lo realiza en cuatro tra= tamientos y se obtiene los siguientes resultados:

Tabla 3=

Pesos = de almidón obtenido

TRATAMIENTO<= span lang=3DES-EC style=3D'font-size:10.0pt;line-height:150%;mso-ansi-language= :ES-EC; mso-bidi-font-weight:bold'>	Recuento	Promedio	Desviación Estándar=
T1	6	1,85	0,0457
T2	6	2,07	0,0474
T3	6	2,16	0,0345
T4	6	2,21	0,0527
Total	24	2,07	0,1445

Fuente: Elaboración propia

La tabla 3 muestra diferentes estadísticos de peso de almidón para cada uno de= los 4 niveles de tratamiento. Según el análisis de ANOVA no existe una diferenc= ia significativa entre tratamientos y el tratamiento 4 presenta mejor tratamie= nto según la figura 1.

Figura 1

Disper= sión por nivel de cada tratamiento de obtención de almidón

<= !--[if gte vml 1]>

Fuente: Elaboración propia

Se caracteriza el porcentaje de amilosa y amilopectina que posee el almidón de garbanzo.

Tabla 4

Compos= ición del almidón de garbanzo

Análisis

Método

Método referencial

Valor

(%)

Amilosa

19,00

Amilopectina

81,0

Fuente: Elaboración propia

Los almidones con alto contenido de amilopectina promueven la gelificación y la formación del biofilm. Este polisacárido con un entrecruzamiento molecular elevado facilita la polimerización y su composic= ión está alrededor de 81 % según tabla 4.

Tabla 5

Análisis del almidón

Ensayos	Método de análisis	Unidades	Valor
pH	AOAC 954.01	<= span lang=3DES-EC style=3D'font-size:10.0pt;mso-ansi-language:ES-EC;mso-bidi-f= ont-weight: bold'>-	4,531
Humedad	AOAC 962.09	<= span lang=3DES-EC style=3D'font-size:10.0pt;mso-ansi-language:ES-EC;mso-bidi-f= ont-weight: bold'>%	5,84
Densidad aparente	<= span lang=3DES-EC style=3D'font-size:10.0pt;mso-ansi-language:ES-EC;mso-bidi-f= ont-weight: bold'>SMITH	<= span lang=3DES-EC style=3D'font-size:10.0pt;mso-ansi-language:ES-EC;mso-bidi-f= ont-weight: bold'>g/mL	0,473
Viscosidad	ISI 17-1, 2002	<= span lang=3DES-EC style=3D'font-size:10.0pt;mso-ansi-language:ES-EC;mso-bidi-f= ont-weight: bold'>mPas	39249
Temperatura de gelatinización	INEN 1456<= /o:p>	<= span lang=3DES-EC style=3D'font-size:10.0pt;mso-ansi-language:ES-EC;mso-bidi-f= ont-weight: bold'>şC	60
Ceniza	AOAC 942.05	<= span lang=3DES-EC style=3D'font-size:10.0pt;mso-ansi-language:ES-EC;mso-bidi-f= ont-weight: bold'>%	0,6095
Proteína	AOAC 954-01	<= span lang=3DES-EC style=3D'font-size:10.0pt;mso-ansi-language:ES-EC;mso-bidi-f= ont-weight: bold'>%	0,6095
Mohos y levaduras	Siembra en masa	<= span lang=3DES-EC style=3D'font-size:10.0pt;mso-ansi-language:ES-EC;mso-bidi-f= ont-weight: bold'>UFC/100mL	Ausencia
Fibra	Gravimétrico	<= span lang=3DES-EC style=3D'font-size:10.0pt;mso-ansi-language:ES-EC;mso-bidi-f= ont-weight: bold'>%	0,132
Coliformes totales	Siembra en masa	<= span lang=3DES-EC style=3D'font-size:10.0pt;mso-ansi-language:ES-EC;mso-bidi-f= ont-weight: bold'>UFC/100mL	<30
Coliformes fecales	Siembra en masa	<= span lang=3DES-EC style=3D'font-size:10.0pt;mso-ansi-language:ES-EC;mso-bidi-f= ont-weight: bold'>UFC/100mL	Ausencia
Solubilidad	Anderson	<= span lang=3DES-EC style=3D'font-size:10.0pt;mso-ansi-language:ES-EC;mso-bidi-f= ont-weight: bold'>%	4,8166

Fuente: Elaboración propia

La caracterización del almidón de garbanzo según tabla 5 demuestra q= ue sus características físicas y microbiológicas son aptas para su trabajabili= dad. La temperatura de gelatinización para su preparación será de 60 C según resultados.

Los bioplásticos de obtenidos se someten a pruebas de solubilidad:

Tabla 6

Porcen= taje de solubilidad del bioplástico

TRATA= MIENTOS	REPET= ICIONES	PORCE= NTAJE DE SOLUBILIDAD %
A1	R1	63,72
R2	64,61
R3	64,84
A2	R1	62,10
R2	64,20
R3	61,99
A3	R1	56,06
R2	58,02
R3	56,13
A4	R1	60,44
R2	55,16
R3	56,34

Fuente: Elaboración propia

La tabla 6 muestra diferentes estadísticos de porcentaje de solubili= dad % para cada uno de los 4 niveles de tratamiento.

Figura 2

Disper= sión por nivel de cada tratamiento

Fuente: Elaboración propia

Según ANOVA no existe una diferencia significativa entre tratamientos. La prueba = A4 presenta menor solubilidad como se aprecia en figura 2.

Las cuatro formulaciones se ensayan para determinar las propiedades mecánicas d= el bioplástico según la tabla 7.

Tabla 7

Propie= dades mecánicas del bioplástico

TRATAMIENTO	FUERZA(N)	RESISTENCIA A LA TENCIÓN (N/ cm²)	% Elongación
A1	2,0	100	43,33
A2	5,9	295	60,00
A3	3,9	195	53,33
A4	3,9	195	63,33

Fuente: Elabor= ación propia

Figura 3

Propie= dades mecánicas del bioplástico

Fuente: Elaboración propia

Según la figura 3, el tratamiento A2 es el que mejor propiedad mecánica tiene en comparación a las otras muestras de bioplásticos.

Las pruebas de biodegradabilidad se las realiza en condiciones ambientales, en tierra y agua por 30 días.

Tabla 8

Biodegradabilidad en condiciones ambientales durante 30 días (%)

TRATAMIENTO	Condiciones ambientales	Tierra	Agua
A1	9,94	42,13	61,96
10,10	57,49	97,97
12,33	20,45	57,14
9,90	49,02	95,51

Tabla 8

Biodegradabilidad en condiciones ambientales durante 30 días (%) (c= ontinuación)

TRATAMIENTO	Condiciones ambientales	Tierra	Agua
A2	5,53	45,36	57,37
10,09	56,12	93,33
10,99	23,62	53,77
10,42	74,74	97,97
A3	5,00	40,87	52,55
11,70	52,94	88,06
12,62	46,11	44,83
5,47	40,20	41,01
A4	8,05	43,05	54,49
9,80	53,33	69,86
16,34	43,75	45,34
6,41	48,34	91,89

Fuente: Elaboración propia

Respecto a la biodegradabilidad el tratamiento A4 es el que mayormen= te se degradó en condiciones ambientales con una media de 10,15% en comparació= n a los otros tratamientos. Mientras que en tierra el tratamiento A2 se degrado= en mayor proporción durante 30 días con una media en porcentaje de biodegradabilidad de 49, 9581%. Sin embargo, en un medio con agua es donde = se degrado mayormente cada uno de los tratamientos analizados A1, A2, A3, A4 d= onde el A2 es el que se degrado en mayor proporción con una media en porcentaje = de biodegradabilidad de 75,61% con una desviación estándar de 23,27 según tabla 8.

Conclusiones
·         El tratamiento T4 para la obtenci= ón de almidón por vía húmeda obtuvo un rendimiento de 2,21 % y una desviación estándar de 0,053 del grupo de datos con una técnica de trituración de 60 m= in.

·         La caracterización fisicoquímica = del almidón de garbanzo demuestra un 81% de contenido de amilopectina, una temperatura de gelatinización de 60 şC y una solubilidad de 4,81%.

·         Las formulaciones ensayadas para = la obtención del bioplástico muestran después de un análisis estadístico globa= l en cada una de sus pruebas realizadas al bioplástico que el tratamiento A2 es = la que mejor resultó, su formulación fue de 1,5 mL de glicerina,4 mL de ácido acético,1,5 g de almidón de garbanzo y 35 mL de agua destilada.<= /span>

·         El biopolímero obtenido presenta propiedades de biodegradabilidad durante 30 días en condiciones ambientales normales, tierra y agua. Sin embargo, en condiciones acuosas presentan una biodegradabilidad mayor al 50%.

·         Las propiedades mecánicas de tratamiento A2 presentan resultados que cumplen con la Norma NTE INEN 2635:= 2012 Métodos de ensayo para las propiedades de tracción de láminas delgadas. Est= os resultados son comparables con las láminas delgadas de polietileno de baja densidad que permitirían usarse en envoltura para alimentos.

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