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Estudio comparativo de las propiedades fisicoquímicas y microbiológicas de tres tip= os de lactosuero (ovino, bovino y caprino) para uso alimentario.

 

Comparative study = of physicochemical and microbiological properties of three types of whey (bovi= ne, ovine and caprine) for food use.

 

Nora Tahirí Mejía Cabezas. [1], = Diana Katherine Campoverde Santos. [2] <= /span>& Luis Antonio Velasco Matveev. [3]

 

Recib= ido: 28-06-2021 / Revisado: 06-07-2021 /Aceptado: 25-07-2021/ Publicado: 05-08-2= 021

 

Abstract.                                      DOI: https://doi.org/10.33262/concienciadigita= l.v4i3.1.1831

Introduc= tion. Whey is a by-product of cheese production, containing mainly lactose, prote= ins, minerals, vitamins and fat. Its composition varies considerably depending on the type of milk, type of cheese produced and the technological process use= d, but in general it represents between 85% and 95% of the volume of milk and retains 55% of its nutrients. The amount of whey obtained for each kilogram= of cheese is approximately 9 liters, which is why its proper use is of great importance. Objective. The objective of the present study was to evaluate t= hree types of whey: bovine, ovine and caprine. Methodology. The analyzes were carried out in a bromatological laboratory of a private company, where phys= ical variables such as pH and density were analyzed; chemical variables such as = dry extract, ash, protein, fat, calcium and, lactose; also<= /span> microbiological variables such as the coliform population. Results. Signifi= cant differences were obtained at p <0.05 and at p <0.01 in the samples. S= heep whey was the one that registered the best results for total solids with 7.4= 8%, in proteins it contributed 1.05% and, fats with 0.73%. Calcium, pH, density and, lactose did not show significant differences between the wheys analyzed. The goat whey presents coliform level= s of 1.89 Log10UFC • ml-1, being higher than the others. Conclusion. It was concluded that sheep whey is the most suitable for the production of protein concentrates, food and also for the pharmaceutical industry.

Keywords: Whey, goat, sheep, bovine.

 

Resumen.

Introducción. El lactosuero es un subproducto que resulta de la elaboración del queso, conti= ene principalmente lactosa, proteínas, minerales, vitaminas y grasa, su composi= ción varía considerablemente dependiendo del tipo de leche, tipo de queso elabor= ado y el proceso de tecnología empleado, pero en general representa entre el 85= % al 95% del volumen de leche y retiene el 55% de sus nutrientes. La cantidad de suero obtenida por cada kilogramo de queso es de 9 litros aproximadamente, motivo por el cual darle un uso adecuado es de gran relevancia. Objetivo= . El objetivo del presente estudio fue evaluar tres tipos de lactosuero: bovi= no, ovino y caprino. Metodología. El análisis estadístico utilizado fue = el diseńo completamente al azar. Las pruebas se realizaron en un laboratorio bromatológico de una empresa privada, en donde se analizaron variables físi= cas como el pH y la densidad; variables químicas como el extracto seco, cenizas, proteínas, grasas, calcio, lactosa y una variable microbiológica denominada como población de coliformes. Resultados. Se obtuvieron diferencias significativas al p<0.05 y al p<0.01 en las muestras. El lactosuero ovino fue el que mejores resultados registró para sólidos totales con un 7.48%, en proteínas aporta un 1.05% y grasas con un 0.73%. El calcio, pH, densidad y lactosa no presentaron diferencias significativas entre los sueros. El suero caprino presenta niveles de coliformes de 1.89 Log10UFCˇml-1, siendo superior a los otros. Conclusión. Se concluyó que el lactosuero ovino es= el más adecuado para la elaboración de concentrados proteicos, alimentos y tam= bién para la industria farmacéutica.

Palabras claves: Lactosuero, caprino, ovino, bovino.

 

Intro= ducción.

El suero de leche o lactosuero es un subproducto que res= ulta de la elaboración del queso, el cual es obtenido después de la precipitació= n de la caseína, contiene principalmente lactosa, proteínas como sustancias de importante valor nutritivo, minerales, vitaminas y grasa. La composición y = tipo de lactosuero varía considerablemente dependiendo del tipo de leche, tipo de queso elaborado y el proceso de tecnología empleado.(Adolfo & Huertas, 2008)

Existen dos tipos de suero, el lactosuero ácido con un p= H de 4.5 y el lactosuero dulce que tiene un pH de entre 6.0 y 6.5 (Gómez Soto & Sánchez Toro, 2019). Los lactos= ueros dulces surgen de la fabricación de quesos frescos de pasta blanda, obtenido= s a partir de leche de vaca y/o de cabra; en ellos, la lactosa se ha transforma= do en ácido láctico, son ricos en calcio y fósforo, en cambio un lactosuero du= lce, proviene de la fabricación de quesos de pasta cocida y prensada a partir de leche vaca y oveja; es pobre en ácido láctico (Callejas Hernández et al., 2012). La cantidad= de suero obtenida por cada kilogramo de queso es de 9 litros aproximadamente, motivo por el cual, darle un uso adecuado es de gran relevancia. (Onwulata & Huth, 2008= )

El lactosuero representa aproximadamente, del 85% al 95%= del volumen de leche, y retiene el 55% de sus nutrientes. Estos nutrientes pued= en recuperarse para ser utilizados en diferentes campos como los alimentarios = y farmacéuticos. (Siso, 1996). La lactosa es el principal componente nutritivo (4.5 % p-v), proteína (0.8% p/v), y lípidos (0.5%). (Adolfo & Huertas, 2008)

El lactosuero casi siempre ha sido conside= rado como un desecho con poco valor comercial. Su destino sigue siendo uno de los problemas más serios que enfrenta la industria láctea a nivel mundial. (Araujo Guerra et al., 2013) En el mercado exis= ten productos que incluyen al lactosuero como ingrediente, principalmente como medio para aumentar los sólidos lácteos a un bajo costo y, en menor grado, = para aprovechar algunas de sus propiedades funcionales de las proteínas del suer= o. (Alvarado Carrasco &am= p; Guerra, 2010)<= /p>

Para el ańo 2017, la producción de queso a nivel mundial= se estimó en 20 015 000 toneladas. Se calcula que esta cantidad de queso produ= jo 180 135 000 toneladas de lactosuero aproximadamente (Huertas, 2009)<= span lang=3DES-EC style=3D'font-size:12.0pt;line-height:115%;font-family:"Times = New Roman",serif; mso-fareast-font-family:"MS Mincho";color:red;mso-ansi-language:ES-EC'>

Para el ańo 2016 se produjeron en el mundo 21 800 tonela= das de leche de cabra y 13 800 toneladas de leche ovina. De esto el 90% se util= iza para preparar quesos (Ghibaudi et al., 2018; INEC, 2002)   =   

Ecuador destina 1.5 millones de litros de leche para la producción formal de 300 000 kilos de quesos por día. Eso genera 1.2, millo= nes de litros de suero, aunque solo el 10% de este total estaría usándolo la industria para fabricar en su mayoría bebidas lácteas. (el Universo, 2019)

Este suero es suficient= e para alimentar a 120 000 personas por día. Sin embargo, debido a los acuerdos ministeriales gran parte de este producto no se comercializa y termina desperdiciándose como comida para cerdos de traspatio y vertiéndose sobre el sistema de alcantarillado público o quebradas. El desperdicio del suero gen= era un grave problema ambiental que va en contra de las iniciativas mundiales relacionadas a los objetivos de Desarrollo Sostenible, Economía Circular, e= ntre otros.

El martes, 17 de septie= mbre de 2019, la Asamblea Nacional introdujo entre las reformas al Código Orgáni= co Integral Penal (COIP) la sanción a la oferta o venta del suero de leche con fines comerciales en la cadena láctea, excepto si se encuentra concentrado.= ( https://www.primicias.ec/noticias= /economia/suero-leche-industria-agronomia-lactosuero/) <= /span>

En general, resulta interesante mirar las propiedades existentes en la leche de una amplia gama de mamíferos para comparar las variaciones en composición entre las diferentes especies. La mayoría de los sueros se generan a partir del procesamiento de las leches de vaca, oveja y cabra, porque son las de mayor importancia a nivel mundial, siendo la leche= de vaca la más producida y utilizada. (Zadow, 1992)

En el presente estudio se analizarán las propiedades fisicoquímicas y microbiológicas del lactosuero ovino, bovino y caprino. Materia seca, cenizas, proteína, lactosa, grasa, calcio, acidez, fosfatasa,= pH y densidad, son aquellas catalogadas como propiedades fisicoquímicas, mient= ras que la cantidad coliformes presentes será el parámetro establecido para hab= lar sobre sus propiedades microbiológicas.

El lactosuero contiene muchas sustancias biológicamente activas, que pueden actuar como agentes antibacterianos y antivirales modificadores, además contiene varios componentes que pueden proteger contra toxinas, bacterias y virus. Estos componentes incluyen inmunoglobulinas, calostro, lactoferrinas (LF) y sus derivados peptídicos, como lactoferrina,= lactoperoxidasa, glicomacropépti= dos (GMP) y esfingolípidos (Fl= oris et al., 2003; Shukla et al., 2017). Es m= ás, los péptidos antimicrobianos se pueden generar a partir de proteína de suero por proteólisis durante el tránsito gastrointestinal.

El papel antimicrobiano de las LF es de particular inter= és para la función intestinal y la prevención de enfermedades gastroentéricas mediante el control de la microflora intestinal. Mientras que LF exhibe actividad bactericida contra patógenos como coliformes, también proporciona soporte probiótico para microorganismos beneficiosos como Bifidobacteria y = Lactobacilli ssp. (Yamauchi et al., 2006), e incluso varios estudios han reportado que la administración diaria de LF suprime positivamente la colonización intestinal de He= licobacter pylori, el cual se conoce como agente causal en la mayoría de las úlceras duodenales y se cree que es responsable del 50% -60% de todos los carcinomas gástricos (Collins et al.,= 2006).

En la actualidad, el principal uso para el lactosuero es= en la industria alimentaria, para elaborar concentrados o aislados proteicos, suplementos y un sin número de productos con un alto valor nutricional, deb= ido a la gran producción de leche de vaca, la cual es conocida como un alimento= de primera necesidad, la mayor cantidad de investigaciones relativas al tema se enfoca= n en el estudio del lactosuero bovino, a diferencia de lo que ocurre con el suero bovino, de los cuales existe poca información disponible.  

= Metodología.

El estudio se realizó= en un laboratorio bromatológico de una empresa privada, para ello se utilizaron 3 muestras de suero de distintas especies (ovino, caprin= o y bovino) con la finalidad de determinar las propiedades fisicoquímicas (extr= acto seco, cenizas, proteína, lípidos o grasas, calcio, lactosa, pH, densidad) y microbiológicas del lactosuero. A continuación, se detalla el proceso de determinación de cada variable:

Extracto Seco

El extracto se= co es todo lo que queda una vez eliminada la humedad del suero. Se utilizó la desecación del suero en estufa a una temperatura de 105°C. Previo al anális= is la muestra fue homogenizada para seguir el proceso correspondiente. En prim= er lugar, se determinó la humedad, pesando las muestras líquidas y las sólidas= una vez realizado el proceso de desecado. 

El contenido s= eco se calculó restando el contenido líquido del peso total de la muestra y se exp= resó el extracto seco en función de porcentaje mediante la fórmula

Cenizas=   

Se incineraron muestras de cada tipo de lactosuero exactamente pesadas en un crisol de porcelana utilizando una mufla a una temperatura de= 500° durante 7 horas.  Cuando la muestra= se encuentra libre de partículas carbonosas y las cenizas presentan un color blanco o gris uniforme, el proceso se da por terminado y se pesa utilizando= una balanza analítica para obtener resultados precisos. Al igual que el conteni= do de extracto seco, el contenido de cenizas se expresa en porcentaje.

Proteína

La cantidad de proteínas existente en cada una de las muestras= de suero se determinó mediante precipitación por sales. Una vez obtenido el precipitado, se utilizó el método gravimétrico para obtener un valor exacto= y el resultado se expresó en porcentaje.

Lípidos o grasas

Los lípidos en las muestras de lactosuero fueron obtenidos mediante butirometría. Para separar las grasas = se colocó ácido sulfúrico y posteriormente se llevó a cabo un proceso de centr= ifugación, que evita la carbonización y finalmente se desenmulsionaron las grasas se ańade alcohol amílico.

Calcio

La determinación del Calcio se la realizó utilizando un espectrofotómetro, en = el cual se tomó 5ml de suero de leche en un matraz, se adicionó 50 ml de ácido tricloroacético al 24% y agua desionizada, esta mezcla fue agitada de forma moderada cada 5 minutos por 30 minutos. Luego se filtra la disolución y se = desechó la parte sólida. Luego se toma una muestra de 5ml de la disolución y se le ańadió 1ml de cloruro de lantano. Esta mezcla fue llevada al equipo para su= medición por triplicado.

Lactosa<= /span>

La lacto= sa se midió siguiendo la norma AOAC 984.15, método enzimático mediante la hidr= ólisis de lactosa.

pH

La determinaci= ón del pH en el suero se lo realizó mediante el uso de un medidor digital prev= iamente calibrado, mismo que es introducido en la muestra directamente.<= /span>

Densidad<= /o:p>

Se la determinó con el uso de un termo lactodensímetro Quevenne= 15-40 que fue introducido en las muestras de suero.

Coliformes

Estos microrganismos fueron evaluados mediante el método de vertido en placa siguiendo la norma ISO 9308-1:2014, se procuró realizar un correcto homogen= izado de las muestras, dejándolas incubar por 48 horas a 35°C.<= /p>

Con el propósito de identificar de identificar y evaluar las características fisicoquímicas y microbiológica se realizó un estudio transversal y con los datos obtenidos = se aplicó un diseńo experimental, por consiguiente, se aplicó un análisis de varianza de un factor, para determinar si existen diferencias significativa= s en esos variables de las diferentes especies.

Resultados.

Al analizar la cantid= ad de contenido de extracto seco del suero nos referimos al residuo expresado = en porcentaje de peso obtenido después de la efectuada desecación de la leche, está compuesto principalmente por proteínas, lactosa como sustancias de sus= tancial valor nutritivo, grasas, vitaminas, cenizas, calcio y lactosa, la figura 1 representa los valores porcentuales encontrados en cada una de las especies= .

Figura 1

Extracto seco (%) de las muestras de lactosuero

            Fuente: Elaboración propia.

El lactosuero constituye una fuente económica para= la industria alimentaria, al contener proteínas que proporcionan diversas propiedades en= una extensa gama de alimentos, al referirnos de los derivados del suero (etanol, bebidas no alcohólicas y fermentadas, ácidos orgánicos, aislados, concentra= dos e hidrolizados de proteína)  matiza= mos la importancia de la lactosa el cual es una propiedad que realza el color y sa= bor, mejoran la textura y presentan otras propiedades que permiten aumentar la calidad de los alimentos, es por esto la preocupación que genera que se esté utilizando este líquido para alimentar a los cerdos en forma extensiva en l= os hogares y sectores rurales, además de que una gran parte de este sea desech= ado en los drenajes y en las quebradas, siendo el suero un alto contaminador del medio ambiente ya que por su pH acidifica los suelos y provoca inmovilizaci= ón de metales pesados, en el agua destruye su ecosistema al requerir grandes cantidades de oxígeno para su degradación, además que eutrofiza las aguas c= on poca corriente.    

Tabla 1

Análisis de las propiedades fisicoquímicas y microbiológicas de las muestras de suer= o

Propiedad

Caprino

Ovino

Bovino

Extracto seco (%)

6.64b

7.48a

6.34b

Cenizas (%)

0.61a

0.498c<= /span>

0.58b

Proteína (%)

0.77b

1.05a

0.73b

Lípidos o grasas (%)

0.51b

0.73a

0.47b

Calcio (%)

0.04a

0.06a

0.05a

Lactosa (%)

4.71a

5.13a

4.61 a

pH

6.29a

6.31a

6.22a

Densidad (g/ml)

1.003a

1.058a

1.115a

Coliformes (%)

1.89a

1.45b

1.31b

Los resultados en la misma fila con diferentes letras en superíndice difieren significativamente (p ≤ 0.05) según la prueba de Tukey.

Fuente: Elaboración Propia.

La tabla 1 presenta un cuadro de resumen de los resultados obtenidos en cada una de las variables estudiadas en cada especie (caprino, ovino y bovino), en lo que se refiere a la cantidad de contenido en extracto seco del lactosuero de oveja es más alto = que el de la vaca y cabra (altamente significativa con un p<0.01), por el contrario, este parámetro no presentó diferencias significativas entre la cantidad de extracto seco en l= as especies caprina y bovina.

El contenido de ceniz= a en el lactosuero de la oveja es menor que el contenido obtenido de la cabra y = la vaca, los valores reportados con anterioridad evidencian diferencias altamente significativas (p<0.01) entre el suero de la especie caprina respecto a la especie ovina y bovina, = así mismo la cantidad de contenido de cenizas en el lactosuero de la vaca y ove= ja (p<0.05) presentan diferencias significativas. Estos resultados coinciden con los hallazgos encontrados por Keskin et al. (2004) = y Bhosale et al. (2009) respecto a la cantidad de conte= nido de cenizas encontrada en la leche de vaca, de igual manera respecto a la cantidad de contenido de cenizas encontrado en el lactosuero de caprinos coincide con los resultados reportados en una investigación realizada por Sanmartín (2010), agregando a lo anterior los valores obtenidos del conteni= do de cenizas en el lactosuero de la leche ovina son similares a los resultado= s de Adewumi y Olorunnisomo (2009).

Seguidamente no existieron diferencias significativas (p>0.05) entre las proteínas del lactosuero de las especies caprinas y bovinas, por otro lado, la cantidad de contenido de proteína en la leche de oveja fue mayor en comparación al contenido obtenid= o en las otras 2 especies con un nivel altamente significativo (p<0.01). Esta reducción del conteni= do de proteínas depende de la fase de lactancia y el estado de salud de la ubr= e, además los resultados del contenido de proteínas de cada especie coinciden con la revisión bibliográfica encontrada en Imran et a= l. (2008), Abd et al. (2009), Aneja et al (2002) y Pavic<= /span> et al. (2002). Otro aspecto que se puede destacar con relación al suero de leche de oveja es que está representado por un 17-22% del total de proteína= s.

A continuación, se observa que la cantidad de contenido de grasa en el lactosuero de oveja es = más alta que los valores resultantes en las espe= cies bovinas y caprinas de acuerdo con la t= abla sus diferencias son altamente significativa (p<0.01), mientras que el lactosuero de la cabra = y la vaca no presentan diferencias significativas. La cantidad de grasa encontra= da en la lactosa de cabra fue similar a la citada por Bho= sale et al (2009), ahora bien, los hallazgos encontrados en la lactosa de vaca coinciden con la investigación realizada por Mahboba y Zuberir (2007) y Samia et al. (2009), del mis= mo modo al comparar la cantidad de lactosa producida por la especie ovina en e= sta investigación es similar a la información encontrada en las investigaciones= realizadas por Talevski et al., Adewu= mi y Olorunnisomo durante el ańo 2009.

Luego al examinar los resultados de los variables calcio y lactosa demuestran que no hay diferencias significativas entre el contenido obtenido en el lactosuero de las especies caprinas, ovinas y bovi= nas, en contraste con las investigaciones realizadas por By= lund (1995), Lingathurai et al. (2009) y Sawaya et al. (2009) se puede afirmar que los resulta= dos son similares.

Los resultados referentes al pH indican que los su= eros de las tres especies no fueron significativamente diferentes (p> 0.05) entre sí, de acuerdo a los valores obtenidos se puede clasificarlas como suero dulce. (Kim et al., 1989; Casper et al.,1998; Boumba et al., 2001).  Además, el aumento de contenido de prote= ínas ayuda a reforzar la densidad, por lo tanto, tampoco existen diferencias significativas entre las especies.

Por último, se observ= a que el lactosuero de la especie caprina presenta mayor cantidad de coliformes q= ue la cantidad obtenida en la especie ovina y bovina, por esta razón las difer= encias son altamente significativas, esto puede estar ocasionado por una alimentac= ión inadecuada o por una manipulación incorrecta antes o después del ordeńo, de otra forma= se podría indicar que la leche fue tratada incorrectamente durante y después d= el ordeńo, incluidos los procesos de refrigeración y transporte (Haenlein, 1987).

Conclusiones.

ˇ      =    Las técnicas estadísticas realizadas nos p= ermiten identificar al suero de leche ovino como el de mejor calidad ya que posee la mayor cantidad de sólidos totales con un 7.48%, además es el que mayor cant= idad de proteínas aporta con un 1.05% y estas proteínas son las actualmente soli= citadas por la industria alimenticia y de cosméticos. Estos resultados coinciden co= n la revisión de la literatura que indica que el contenido de proteína en el lactosuero de oveja es mayor que en la de cabra o de vaca, es evidente ese contenido varía dependiendo de las especies, adicionalmente se puede afirma= r esto está influenciado por la raza, la ingesta de alimentos, la paridad, la etap= a de lactancia y el estado de salud de la ubre, además se puede destacar que la leche de oveja tiene una muy buena capacidad de coagulación. Además, las es= tas propiedades mencionadas anteriormente se suman las grasas con un 0.73%, de acuerdo a la revisión bibliográfica los lípidos de la leche son algo simila= res a los de la cabra, se diferencian por la presencia de ácidos grasos en mayor proporción en la leche de cabra que en la de oveja.

ˇ      =    Para los niveles de calcio, lactosa, pH y = densidad no existen diferencias estadísticas significativas entre los tres tipos de = lactosuero. Si lo que se busca es obtener azúcar de la leche se podría utilizar cualqui= era de estos sueros con rendimientos similares.

ˇ      =    Microbiológicamente el lactosuero capr= ino es el que mayor cantidad de coliformes posee 1.89 Log10UFCˇml-1, posee diferencias con los otros sueros, aunque no superan los niveles establecidos por la Norma INEN 719.

ˇ      =    La alta producción de lactosuero a niv= el mundial y nacional abre un gran abanico de posibilidades de industrializaci= ón de este producto que retiene gran parte de los nutrientes de la leche y se encuentra subutilizado o contaminando el medio ambiente.<= /p>

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Wulff-Pérez, M., Martín-Rod= riguez, A., Gálvez-Ruiz, M., & de Vicente, J. (2013). The effect of polymer surfactant on the rheological properties of nanoemulsi= ons. Colloid and Polymer Science, 291, 709–716.

 

 

 

 

 

 

 

 

PARA CITAR EL ARTÍCULO INDEXADO.

 

 

Mejía Cabezas, N. T., Campoverde Santos, D. K., & Velasco Matveev= , L. A. (2021). Estudio comparativo de las propiedades fisicoquímicas y microbiológicas de tres tipos de lactosuero (ovino, bovino y caprino) para = uso alimentario. ConcienciaDigital, 4(3.1), 301-313= . https://doi= .org/10.33262/concienciadigital.v4i3.1.1831

 

 


 

 

 

El artículo que se publica es de exclusiva responsabilidad de los autores y no necesariamente reflejan el pensamiento de la Revista Concienc= ia Digital.

 

El artículo qu= eda en propiedad de la revista y, por tanto, su publicación parcial y/o total en otro medio tiene que ser autorizado por el director de la Revista Conciencia Digital.

 

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[1] Escuela Superior Politécnica= de Chimborazo, Facultad de Ciencias Pecuarias, Ingeniería en Agroindustrias, C= himborazo, Riobamba, Ecuador, nora.mejia@espoch.edu.ec, https://orcid.org/0000-0002-03= 08-5412.

[2] Escuela Superior Politécnica de Chimborazo, Facul= tad de Ciencias Pecuarias, Medicina Veterinaria, Chimborazo, Riobamba, Ecuador, di= ana.campoverde@espoch.edu.ec, https://orcid.org/0000-0001-8538-6747.

[3] Escuela Superior Politécnica de Chimborazo, Facultad de Ciencias Pecuarias, Ingeniería Zootécnica Riobamba, Ecuador, lvelasco@espoch.edu.ec, https://orcid.org/0000-0002-4497-576.

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