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 Obtención y determinación de la calidad = de colorante natural de uvilla para uso alimenticio

 =

 

Obtaining and determini= ng the quality of uvilla natural dye for food use

&= nbsp;

Cabrera Escobar José Omar.[1], Marco Raúl Chuiza Rojas.[2], = Raquel Leticia Coba Carrera.[3] &= amp; Sonia Mercedes Vallejo Abarca.[4]

 

Recibido: 12-04-2019 / Revisado: 28-0= 5-209 /Aceptado: 28-06-2019/ Publicado: 25-07-2019

Ab= stract          =            DOI: https://doi.org/10.33262/cienciadigital.v3i3.2.726

The obtaining of the gra= pe dye is focused on the determination of its physical, chemical and microbiological characteristics, for which, we proceeded with the sensory analysis of the fruit, in which, its physical characteristics were determin= ed, subsequently the process identification was performed The most suitable dry= ing by means of three different dehydration equipment, determining that the bes= t option is with the lyophilization equipment, in which, the dry product that meets = the characteristics was obtained to have the best performance in the extraction= of the pigment with ethanol, then the rotary evaporator was purified, recoveri= ng on the one hand and ethyl alcohol with 80% purity and on the other hand the almost pure dye, which is taken to the UV spectrophotometer to identify the structure, for which, a scanning of 400 to 600 nm wavelength, determining t= hat at 427 nm the peak of β-Carotenes is identified, later The proximal and microbiological analysis was performed, parameters that comply with the provisions of the standard for food use. Keywords: Production, food, dye, natural, uvilla, drying, lyophili= zation, extraction

Resumen

La obtención del colorante de uvilla está enfocada en la determinación de sus características físicas, químicas y microbiológicas, para lo cual, se proce= dió con el análisis sensorial del fruto, en el cual, se determinó sus características físicas, posteriormente se realizó la identificación del proceso de secado más adecuado mediante tres equipos de deshidratación diferentes, determinando que la mejor opción es con el equipo por liofilización, en el cual, se obtuvo el producto seco que cumple las características para tener el mejor rendimiento en la extracción del pigmen= to con etanol, luego se procedió a la purificación en el rota vapor, recuperando p= or un lado un alcohol etílico con el 80 % de pureza y por el otro el colorante casi puro, mismo que es llevado al espectrofotómetro UV para identificar la estructura, para lo cual, se efectuó un barrido de 400 a 600 nm de longitud= de onda, determinando que  a 427 nm se identifica el pico de β- Car= otenos, posteriormente se realizó el análisis proximal y microbiológico, parámetros= que cumplen con lo establecido en la norma para uso alimenticio.        

Palabras claves: Elaboració= n, alimentos, colorante, natural, uvilla, secado, liofilización, extracción

Intro= ducción

La industria alimenticia adici= ona colorantes sintéticos (compuestos químicos) a productos de consumo masivo p= or su bajo costo, y porque mejoran sus propiedades organolépticas (vista, gust= o) logrando así impresionar los órganos sensoriales de los consumidores, pero = en estudios efectuados se determina que los productos químicos utilizados en la síntesis de colorantes también se consideran carcinógenos o mutagénicos, así como también sensibilizantes o alergénico, un ejemplo de pigmentos canceríg= enos son los de tipo azoicos que se obtienen de arilaminas. Estudios efectuados han demostrado que los colorantes azoícos tienen potenciales carcinógenos de colon (Hassan & et al, 2004), aumenta el nivel medio de hiperactividad en niños de 3 años, así como también entre 8 y 9 años. (Mccann & et al, 2007), por lo expues= to, se pretende obtener colorantes naturales  (Brito & et al, Obtención y determi= nación de la calidad de colorante a partir de las flores de Sangorache, 2019)  que además de tener fuentes nutricionales ayudan a la salud de los seres humanos.

La uvilla es un fruto (Fischer & Miranda, 2012) silvestre nati= vo de los Andes Ecuatorianos (Choco & Cazar, 2014), con un sabor agridulce, pero con gran cantidad de carbohidratos, provitamina E principalmente, así como β- Carotenos, que son pigmentos naturales hidrosolubles de gran importa= ncia para la industria alimenticia, por tal razón, pueden ser sustituidos como c= olorantes (Brito & et al, Colorantes naturale= s para uso alimenticio, 2019) sintéticos ya que tienen características propiedades antioxidantes que inhi= ben la acción de especies nocivas para el organismo, como los radicales libres = y se asocian con la prevención de enfermedades como el cáncer (Bui, et al., 2004), así como tamb= ién  puede purificar la sangre, reducir la al= bumina de los riñones, aliviar problemas en la garganta, próstata y bronquios, for= talecer el nervio óptico, limpiar las cataratas y prevenir la osteoporosis. (Calvo, 2009, p. 8).

La realización de este estudio= se enfocó en primer lugar en el análisis sensorial (Bergquist & Gertsson, 2017) de la uvilla, estableciendo sus características de tamaño, forma, color, entre otras, lue= go procedió a determinar el equipo de secado más adecuado para este proceso, utilizando tres equipos de deshidratación diferentes, determinando que el secado por liofilización es el mejor, el mismo que obtuvo un producto que cumple las características establecidas para obtener por extracción con solvente (etanol) el pigmento, a continuación se purificó por el método de destilación  (Brito, Texto Básico de Operaciones Uni= tarias II, 2001) en el rota vapor y procedió  al correspondiente análisis de sus características físicas, químicas, microbio= lógicas, así como también el espectro con una longitud de onda de 427 nm determinand= o a los β- Carotenos como compon= ente principal.        

Metodología

El desarrollo de la investigac= ión se enfocó en la extracción del colorante natural (Brito & et al, 2019) de la uvilla p= ara el uso alimenticio mediant= e los procesos de secado, agitación, mezclado, extracción por solventes y destila= do, para obtener un pigmento que cumpla con los estándares de calidad de acuerdo a la norma, mismo que tiene fuentes nutriciona= les y ayudan a la salud de los seres humanos.

La investigación se desarrolló= con el objeto de extraer pigmento natural (Delgado-Vargas & et al, 2004) a partir de la= uvilla, para lo cual, se realizó el análisis sensorial de la fruta (tamaño, forma, aspecto, color, textura, olor), luego se procedió con el secado en tres equ= ipos diferentes (liofilización, bandejas y atomización), con los datos obtenidos= se procedió a valorar cuál de ellos es el más adecuado, determinando que el se= cado por liofilización  (Brito, Texto Básico de Operaciones Uni= tarias III, 2001),  es el más idóneo para obtener la materia prima, misma que es llevada a un equipo soxlet para la extracción del color= ante con el uso del alcohol etílico al 90 %, la mezcla (Brito, Texto Básico de Operaciones Uni= tarias I, 2000) obtenida es llevada a un rota vapor para separar el pigmento líquido del etanol, para ello se trabaja con una temperatura de 45 ºC y 250 mmHg, finalmente al producto obtenido se realiza los análisis de laboratorio físi= co-químicas (Brito, Borja, Chango, & Vacacela, = 2019), cuyos parámet= ros a valorar son pH, temperatura, densidad, índice de refracción y ºBx, en relación a los metales son: zinc, arsénico y plomo, por otro lado, se analizó también la estructura en un espectrofotómetro Uv Visible, para lo cual, se efectuó un barrido con longitudes de onda de 400 a 600 nm, identificando que se encuen= tra los β – Carotenos a 427 nm, finalmente se efectuaron pruebas microbiológicas de mohos y levaduras, parámetros que se encuentran bajo la norma  oficial mexicana nom-119-ssa1-1994= .

Resultados y Discusión

Tabla 1.  Matriz comparativa para la obtención de colorant= e de uvilla

 

No.<= o:p>

Vari= ables

Méto= dos de secado para la uvilla

Band= eja

Liof= ilizador

Atom= izador

1

Tiempo  de secado (h= )

8

9

3,5

2

Temperatura de secado (ºC)

60

55

120

3

Rendimiento (%)

15,30

17,87

2,30

4

Humedad (%)

75,8

73,78

97,48

5

Colorante extraído (%)

47,75

50,7

10,65

         =    Fuente: Walter Macas, Laborator= io de Investigación, 2018.

Las pruebas se las realizaron = en tres equipos de secado determinando que el más adecuado es el de liofilizac= ión se utiliza la temperatura más baja a pesar de requerir mayor tiempo de seca= do.

Tabla 2. % de Error f (% de Humedad eliminada)

% Humedad =

Práctico

% Humedad Teórico

% Error

1

Secador de Bandejas

75,801

78,9*

0,04

2

Secador por Liofilizador

73,779

0,06

3

Secador por Atomización

97,481

0,24

         =    Fuente: Walter= Macas, Laboratorio de Investigación, 2018. * Castro, et al., 2008, p. 228

El porcentaje de error más baj= o es el procedente del proceso de secado por bandejas y el más alto el de atomización, cabe señalar que a pesar de ser un valor mayor el de liofiliza= ción es el más adecuado por la temperatura menor y porque se mantienen las propiedades del producto.

Tabla 3. Análisis estadístico de la varianza a los paráme= tros físico químico

No.<= o:p>

Anál= isis

Frut= o

 

Colo= rante

Vari= anza (T)

1

pH

3,66

 

4,70

***

2

ρ (g/mL)

0,9863

 

0,9154

***

3

° Bx

14,7766

 

17,5334

**

4

Nd

1,3920

 

1,3593

**

5

%ST

8,2050

 

22,0403

***

Nota:(***=3Dp<0,001), (**=3Dp<0,01), (*=3Dp<0,05), (NS=3Dp>0,05)

         =    Fuente: Walter Macas, Laborator= io de Investigación, 2018.

 

Del análisis estadístico se desprende la siguiente información: es muy significativo en el pH con un ni= vel de confianza de 99,9 %; un nivel muy alto de significancia para la densidad= con un grado de confianza de 99,9%, es significativo en el ° Bx y nD con un niv= el de confianza de 95%.

Tabla 4. Datos de longitud de onda y absorbancia

Longitud de onda _= 5; (nm)

Absorbancia

Luego de realizar el barrido de 400 a 600 nm de longitud de onda en el espectrofotómetro UV se determina qu= e el valor más adecuado y donde se determina la presencia de β- Carotenos es de 427 nm correspondiente inicialmente al proces= o de secado por liofilización.

Tabla 5. Análisis microbiológico – Metales  

 

No.=

Parámetro<= /span>

Valor Referencia=

Experimental

 

Los análisis de los parámetros= de metales se encuentran por debajo de la norma oficial mexicana nom-119= -ssa1-1994, y existe ausencia de mohos y levaduras en el microbiológico.

 

Con= clusiones.

ü  Del análisis de los p= arámetros físico químicos se desprende los siguientes resultados: pH de 4,70; la dens= idad de 0,95 g/mL; los °Bx de 10,69; el índice de refracción de 1,36 y los sólid= os totales de 22,04 %.

ü=   El método de secado ó= ptimo es por Liofilización.

ü=   La temperatura de sec= ado es de 55 0C.

ü=   El rendimiento de ext= racción de colorante es del 50,70 %.

ü  El colorante obtenido= cumple con los parámetros de Arsénico, plomo y zinc, así como también para mohos y levaduras.

 

Referencias bibliográficas

 

Bergquist , S., & Gertsson. (2017). Ascorbic acid,carotenoids, and visual quality of baby spinach as affected by shade netting and postharvest storage. Journal of Agricultura= l and Food Chemistry. Journal of Agricultural and Food Chemistry.

Brito, H., & et al. (2019). Obtención del colorante natural del Camote (Ipomoea batatas). Ciencia Digital, 38-47.=

Brito, H. (2000). Texto Básico de Operaciones Unita= rias I. Riobamba, Chimborazo, Ecuador: Docucentro ESPOCH.

Brito, H. (2001). Texto Básico de Operaciones Unita= rias II. Riobamba: Docucentro ESPOCH.

Brito, H. (2001). Texto Básico de Operaciones Unita= rias III. Riobamba: Docucentro ESPOCH.

Brito, H., & et al. (2019). Colorantes naturales p= ara uso alimenticio. Ciencia Digital. doi:10.33262/cienciadigital.v3i2.4.510

Brito, H., & et al. (2019). Obtención y determinac= ión de la calidad de colorante a partir de las flores de Sangorache. Cienc= ia Digital.

Brito, H., Borja, D., Chango, G., & Vacacela, P. (2019). Obta= ining Yacon Flour (Smallanthus sonchifolius). International Journal of Curre= nt Research and Academic Review.

Bui, A, V., Ngyen, M, H., & Joachim, M. (2004). laboratory study on glucose concentration by osmotic = distillation in hollow fibre module. JOURNAL OF FOOD ENGINEERING, 237-245.<= /o:p>

Calvo, I. (2009). EL CULTIVO DE LA UCHUVA (Physalis peruviana). Microcuenca Plantón - Pacayas(10), 1-112.

Choco, O., & Cazar, M. (2014). Variación del potencial antioxidante durante la maduración de uvilla y su estabilidad frente a tratamientos térmicos. Cuenca.

Delgado-Vargas, F., & et a= l. (2004). Natural pigments:. Critical Reviews in Food Science and Nutrit= ion, 173-289. Obtenido de https://www.clinicalkey.es/service/content/pdf/watermarked/1-s2.0-S014067= 3607613063.pdf?locale=3Des_ES

Fischer, G., & Miranda, D. (2012). Uchuva (Physalis peruviana L.). En Manual para el cultivo de frutales en el trópico (págs. 851-= 873). Bogotá: FISCHE R, G. (Ed.).

Hassan, O., & et al. (2004= ). Extracts of cocoa (Theobroma cacao L.) leaves and their antioxidation potential. Food Chemistry.

Mccann, D., & et al. (2007= ). A Randomised, Double-Blinded, Placebo-controlled Trial. Food additives a= nd hyperactive behaviour in 3-year-old and, 1560-1567. Obtenido de https= ://www.clinicalkey.es/service/content/pdf/watermarked/1-s2.0-S0140673607613= 063.pdf?locale=3Des_ES

 

 

 

 

 

 

PARA CITAR EL ARTÍCULO INDEXADO

 

José Omar, C., Chuiza Rojas, M., Coba Carrera, R., & Vallejo Abarca, S. (2019). Obtención y determinación de la calidad de color= ante natural de uvilla para uso alimenticio. Ciencia Digital, 3(3.2), 193-200.= https://doi.org= /10.33262/cienciadigital.v3i3.2.726

 <= /o:p>


 

 

El artículo que se publica es = de exclusiva responsabilidad de los autores y no necesariamente reflejan el pensamiento de la Revista Ciencia Digital.

El artículo queda en propiedad de la revista y, por tanto, su publicación parc= ial y/o total en otro medio tiene que ser autorizado por el director de la Revista Ciencia Digital.

 

 

 

 


[1]  Escuela Superior Politécnica de Chimborazo, Facult= ad de Ciencias Pecuarias. Riobamba, Ecuador. jose.cabrera@espoch.edu.ec=

[2] Esc= uela Superior Politécnica de Chimborazo, Facultad de Ciencias. Riobamba, Ecuador= . raulma= rch_07@hotmail.com

[3] Escuela Superior Politécnica de Chimborazo, Facultad de Ciencias. Riobamba, Ecuador. raquel.coba@espoch.edu.ec

[4] Escuela Superior Politécnica de Chimborazo, Facultad de Ciencias. Riobamba, Ecuador. soniavallejoa@yahoo.com

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