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Eficiencia socio ambiental de la reacción fenton en el tratamiento de lixiviados =

 

 

Socio-environmental efficiency of the Fenton reaction in the treatment of leachate

 <= /span>

José Gerardo León Chimbolema.[1], = Sofía Carolina Godoy Ponce. [2] & Mayra Alexandra Guevara Villegas. <= /span>[3]

 

Recibido: 24-04-2020 / Revisado: 22-05-2020 / Aceptado: 24-06-2020 / Publicado: 03-07-2020=

 

Abstract.         =                                   DOI:  https://doi.org/10.33262/cienciadigital.v4i3.1334     

The research work focused on determining the conditions of socio-environmental efficiency of the Fenton process for the treatment of leachates from a landfill. The cost-benefit assessment of soci= al and environmental variables of the treatment in winter and summer time has = been carried out through the analysis of externalities and a strategic diagnosis defined by the area of direct influence and the chemical physical quality of the leachate to from the concentrations of ferrous sulfate, hydrogen peroxi= de, pH, optimal dose with jug test, turbidity and color. When the sanitary land= fill was cataloged as a young landfill, from the results generated there were parameters with high concentrations, so the treatment process required opti= mal conditions of 400 mg / L for hydrogen peroxide, 1000 mg / L for ferrous sul= fate and a pH of 3, values that generated an efficiency of 85% for biochemical oxygen demand, 73% for chemical oxygen demand, 91.0% turbidity and 33.3% alkalinity. These last parameters were indicators that the process represen= ts a high socio-environmental cost - benefit for the sector under study.

Keywords: fenton, leached, socio-environmental efficiency, cost-benefit, treatment.

Resumen.

El trabajo de investigación se centró en la determinación de las condiciones de eficiencia socio ambiental del proceso Fenton para el tratamiento de lixiviados de un relleno sanitario. Se ha llevado a cabo la valoración costo-beneficio de variables sociales y ambientales del tratamiento en época de invierno y ver= ano a través del análisis de externalidades y de un diagnóstico estratégico definido por el área de influencia directa y de la calidad físico química del lixiviado a partir de las concentraciones de sulfato ferroso, peróxido de hidrógeno, pH, dosis óptima con prueba de jarras, turb= idez y color.  Al ser catalogado el rell= eno sanitario como un relleno joven, de los resultados generados existieron par= ámetros con concentraciones altas, por lo que el proceso de tratamiento requirió de condiciones óptimas de 400 mg/L para peróxido de hidrógeno, 1000 mg/L para sulfato ferroso y un pH de 3, valores que generaron una eficiencia de 85 % = para la demanda bioquímica de oxígeno, 73 % para la demanda química de oxígeno, = 91,0 % de turbidez y 33,3 %  de alcalinidad. Estos últimos parámetros fueron indicadores de que el proceso representa un costo – beneficio socio ambiental alto para el sector objeto de estudio.

Palabras claves: fenton, lixiviado, eficiencia socio ambiental, costo-beneficio, tratamiento.

Introducción.

El incremento de la producción de desechos sólidos industriales, agrícolas y domésticos trae consigo consecuencias de carácter socio ambientales que requieren la acción efectiva de tratamientos tecnológicos sostenibles. El lugar de disposición final de los residuos sólidos lo constituyen en la mayoría de los casos los= rellenos sanitarios, lugar representativo de depósito de lixiviados y de concentraci= ón contaminante a efecto de acumulación de los residuos sólidos (Basanta, García Delgado, Cervantes Martínez, Mata Vázqu= ez, & Bustos Vázquez, 2007). 

Mecanismos implica= dos para la gestión apropiada de residuos sólidos urbanos involucran su tratami= ento y disposición final, para ello se efectúa una valoración de sus impactos ambientales significativos relacionados con los gases de vertedero y lixivi= ados generados (Pellón Arrechea, López Torres, Espinoza Llórens, & González Díaz, 2015).

Los indicadores ambientales y económicos de los sistemas de gestión ambiental de residuos se basan el análisis y =
costeo del ciclo de vida. La evaluación de impactos ambientales en el análi=
sis costo beneficio socio ambiental en América Latina actualmente considera=
 aspectos de procesos primarios de producción y reciclaje. El análisis econ=
ómico incluye costos operativos y de inversión a los costos de las external=
idades ambientales, permitiendo así el análisis de los costos totales para =
la sociedad (Paes, y otros, 2020)

 

Los lixiviados son considerados líquidos en cont= acto con los desechos de rellenos sanitarios y el agua.  Son los líquidos percolados que se form= an como resultado de la biodegradación, arrastre y filtración de la materia or= gánica e inorgánica ( Sáez & Urdaneta , 2014). El lixiviado presenta una composición variable y de elevada toxicidad, por lo = que no es posible comparar resultados con otro, esto implica que debe ser caracterizado y evaluado de manera independiente ( Sáez & Urdaneta , 2014). Los lixiviados contienen altas concentraciones de Carbono Orgánico Total (COT), Demanda Bioquímica de Oxígeno (DBO5) y Demanda química de Oxígeno (DQO), indicadores de la presencia de compuestos orgánicos y sustancias inorgánicas, elevados sólidos totales y disueltos, entre otros. Esta composición depende de la composición de los desechos y de su estabilizació= n (Borzacconi et al= ., 1996).

Los tratamientos c= onvencionales de lixiviados conllevan un alto costo de construcción, operación y mantenimiento, sin embargo, los resultados de remoción de carga contaminant= e en muchos casos son deficientes, por este motivo se han diseñado métodos alternativos de depuración de bajo costo y efectivos como es el caso de la = tecnología fenton =  (Guevara , Guanoluisa, & de la Torre, 2014). El tratamient= o de los lixiviados se ha convertido así en es uno de los conflictos más relevan= tes y desafiantes de los rellenos sanitarios y las aguas residuales, que motiva= a las organizaciones a considerar tecnologías existentes en el país, económicamente viables y de impacto significativo para la sociedad ecuatori= ana (Guevara , Guanoluisa, & de la Torre, 2014).

Los contaminantes presentes en los lixiviados varían con el tiempo, y no sería posible su tratamiento aplicando un único proceso tecnológico. Los lixiviados jóvenes presentan la relación (DBO5/DBO) mayores a 0.4, lo que implica alta aplicab= ilidad para tratamientos biológicos, sin embargo en lixiviados de rellenos viejos, estos tratamientos son de baja aplicabilidad (Robles, 2005). Al transcurrir el tiem= po la composición va cambiando y la fracción biodegradable disminuye a una relación  (DBO5/DBO) como resultado= de la descomposición a sustancias estables como metano (Lau et al., 2001).

No todos los compuestos orgánicos son biodegradables, sino, sólo aquellos de bajo peso molecular. Los que no son biodegradables presentan una eficiencia limitada frente a tratamientos de tipo biológico (Yoo et al., 2001).  Por su naturaleza requiere uso de proces= os alternos a la biodegradación. Según (Vilar, 2015), se estima que por cada tonelada de residuos sólidos se genera 0.2 m3 de lixiviados y una vez clausurados, la generación de lixiviados puede seguir por más de 50 año= s.

Dentro de Procesos= de Oxidación Avanzada (POA), se encuentra la oxidación Fenton como alternativa viable como pre o post tratamiento biológico (Hermosilla et al., 2009; Oller et al., 2011). Este proceso se sustenta en oxidación química por la formación de radicales libres (*OH) que tienen alto potencial de reducción (Isarain Chávez, 2010).

A fines del siglo = XIX estudios demostraron que la solución de sales ferrosas y de peróxido de hidrógeno era capaz de oxidar compuestos orgánicos (Chevez, 1975),   más tarde (Tang & Tassos, 1997)  sugirieron que se forma radicales (*OH) mediante la siguiente reacción:

 =

=

 =

Estos radicales pu= eden oxidar a la materia orgánica produciendo radicales orgánicos que pueden ser oxidados por Fe3+ con la reacción que se indica (Pignatello, 1992).

=

 =

El proceso Fenton = con base enestudios demuestra que es efectivo para degradar una serie de compuestos que no se degradan por métodos convenciona= les de tratamiento   (Bigda, 1995; Primo, 2008). También existen estudios que ha reducido exitosamente la DQO de aguas residuales municipales y en el tratamiento de lixiviados.=

En la actualidad existen una serie de estudios sobre la eficiencia del reactivo Fenton en la remoción de contaminantes presentes en los lixiviados de rellenos sanitario= s de distintos países. La principal ventaja de tratamiento por proceso Fenton es= que sus componentes son de manipulación simple, económicos y ambientalmente benignos (Kavitha & Palanivelu, 2003).

En el relleno sanitario de la ciudad de Mérida, Yucatán, se realizaron estudios de tratamiento de lixiviado por Fenton donde el tiempo óptimo fue 20 minutos  con concentración de Fe2+  de 1000 mg/L y de 600 mg/L de H2O2  con una remoción de 78 % de DQO = (Méndez et al., 2010). Similarmente se realiz= ó el estudio fenton en la disposición final de Tuxtla Gutiérrez, Chiapas, México lográndose una eficiencia de remoción de DQO en 67 %, también se ha realiza= do el tratamiento de lixiviado del antiguo relleno sanitario “La reserva” por proceso fenton en León, Guanajuato, removiéndose la DQO en 75.3 % ADDIN CSL_CITAT= ION {"citationItems":[{"id":"ITEM-1","itemDa= ta":{"author":[{"dropping-particle":"",&= quot;family":"Mireles","given":"Héctor",= "non-dropping-particle":"","parse-names":fals= e,"suffix":""},{"dropping-particle":"&qu= ot;,"family":"Páramo","given":"Javier&qu= ot;,"non-dropping-particle":"","parse-names":= false,"suffix":""}],"container-title":"R= evista de Ingeniería Tecnológica","id":"ITEM-1","issued":{&qu= ot;date-parts":[["2017"]]},"page":"1-12"= ,"title":"Tratamiento del lixiviado del antiguo relleno sanitario La Reserva mediante procesos Fe= nton y fisicoquímico","type":"article-journal"},"uri= s":["http://www.mendeley.com/documents/?uuid=3D39501c07-a726-4181= -b6ce-93bfa71ff5c6"]}],"mendeley":{"formattedCitation&q= uot;:"(Mireles & Páramo, 2017)","plainTextFormattedCitation":"(Mir= eles & Páramo, 2017)","previouslyFormattedCitation":"(Mireles & Páramo, 2017)"},"properties":{"noteIndex":0},"= ;schema":"https://github.com/citation-style-language/schema/raw/m= aster/csl-citation.json"}(Mireles & Páramo, 2017).

En Perú se realizó= el estudio de optimización de tratamiento fenton en lixiviados de rellenos sanitarios en el que se utilizaron sistemas de jarras con agitación  y la metodología de superficies de resp= uesta, donde se determinó que este sistema puede ser empleado como post-tratamient= o logrando eliminar el 42 % de DQO (Medina et al., 2012, 2016; Medina Valderrama et al., 2018). En el relleno sanitario de Cantón Mejía-Quito Ecuador se realizó el estudio= de lixiviado por oxidación fenton en la cual logró una eficiencia de 90 % de D= QO. En la ciudad de Ambato  quebrada Chazinato, se realizó el estudio de tratamiento de una mezcla de agua residual doméstica con el lixiviado por el método Fenton modificado, obteniendo un rendimiento de DQO de 44.4 % (Sánchez & García Gualoto, 2018). No existen más estudios en el país relacionado al tema en referencia.<= /o:p>

El objetivo de este trabajo fue determinar la eficiencia del proceso fenton en el tratamiento de lixiviados del relleno sanitario “Porlón” de la= ciudad de Riobamba-Ecuador.

Metodologia.

El estudio socioec= onómico requirió de una valoración costo-beneficio a partir de variables sociales y ambientales del tratamiento tanto en época de invierno y verano acompañado = del análisis de externalidades (causa-efecto) y de un diagnóstico estratégico definido por el área de influencia directa y de la calidad físicoquímica del lixiviado a partir de las concentraciones de sulfato ferroso, peróxido = de hidrógeno, pH, dosis óptima con prueba de jarras, turbidez y color. Se sust= entó en la evaluación del grado de aceptabilidad del proceso por parte de la com= unidad que se determinó con base en la aplicación de estrategias sociales de campo como encuestas, entrevistas y grupos focales.

Se realizaron muestreos compuestos durante 6 horas consecutivas desde el eflue= nte de lixiviado del relleno sanitario de Porlón en= la ciudad de Riobamba. Se realizaron valoraciones socioeconómicas y a la muest= ra se la caracterizó a través de pruebas físico-químicas: pH, Sólidos Totales Disueltos (STD), Conductividad, Alcalinidad, Turbiedad, Color, DBO5, DQO y tensoactivos empleando las técnicas establecidas en el Standard Methods (APHA-AWWA-WPCF, 2017).

 

Para determinar la dosis aproximada de hierro se preparó una solución patrón de sulfato ferroso utilizando 1000 mL de lixiviado= al que colocado en el equipo de prueba de jarras a 100 rpm se le adicionó gradualm= ente el volumen de la disolución patrón de hierro hasta que se formaron pequeños flóculos, = a éste valor se consideró como una dosis aproximada de h= ierro. El pH óptimo comprendió valores entre 2 y 4 a partir de ácido sulfúrico con= centrado al 97 % w/w. Para encontrar la dosis óptima de hierro se varió su concentra= ción alrededor de valor de dosis aproximada, éste fue mezclado a 100 rpm durante 1minuto, con una velocidad modificada a 30 rpm por 12 minutos para finalmen= te permanecer en reposo durante 30 minutos más (Méndez, García, Castillo, & Sauri, 2010).

 

La concentración óptima de peróxido de hidrógeno se determinó variándola desde= 200 mg/L hasta 800 mg/L y mezclándola con la dosis de hierro. La mezcla fue agitada  a 100= rpm durante 1 minuto, la velocidad de agitación se modificó a 30 rpm por el lapso de 12 minutos y un tiempo de en reposo de 30 minutos. A partir del mencionado pro= ceso se determinó la turbidez, color y las condiciones óptimas del reactivo fenton, variando el pH a concentración óptima y parám= etros extremos.

 

Para determinar la eficiencia del proceso se realizaron pruebas con los parámetr= os fenton obtenidos por triplicado con su respectiva caracterización antes y después = del tratamiento.

Resultados.

El método empleado trae consigo ventajas comparativas en relación al componente económico: ahorro respecto a procesos convencionales, relacionadas a un dis= eño simple, componente ambiental:  proc= eso que incentiva el máximo aprovechamiento de los recursos naturales y que no genera compuestos estables residuales perjudiciales para la comunidad, componente social: proyecto de innovación,  dentro del marco de la investigación se emplearon tecnologías y metodologías relativamente nuevas que exploraron la capacitad local con el = uso de materiales de trabajo de fácil acceso y manejo en el mercado.

 

En la tabla 1, se presenta resultados de la caracterización de lixiviado en 2 = épocas climáticas (invierno y verano) con los parámetros más importantes.

 

En la tabla 2, se indica los valores de tratamiento realizado y obtenidos como turbidez y remoción de color con sus distintas combinaciones de acuerdo a la metodología planteada.=

 

En la tabla 3, muestra el comportamiento del pH a la variación del reactivo fe= nton, la tabla 4 presenta la eficiencia del proceso bajo condiciones óptimas encontradas en el laboratorio.

 

De acuerdo a los resultados de la tabla 1, el pH se encontró en medio básico y= no existió variabilidad en las épocas del año, estudios realizados en Estados Unidos y Noruega, reportaron valores de pH entre 5,4 y 7 (Sło= mczyńska & Słomczyński, 2004), el valor de pH obtenido se debió al tipo de cobertura empleada en el relleno sanitario (Méndez e= t al., 2010).  

 

La DBO5 representó valores altos tanto en invierno como en verano, 16200 mg/L y 27000 mg/L respectivamente lo que constituyó en un indicador d= e alto contenido de compuestos orgánicos en la fase de acidogénesis entre 2 y 15 a= ños de operación.

 

Cuando el tiempo de operación es mayor a 15 años las concentraciones de éstos parámetros fueron bajos (Sło= mczyńska & Słomczyński, 2004)(Méndez e= t al., 2004), y al comparar los resu= ltados entre las dos épocas del año se definieron diferencias  marcadas con base en una inapropiada impermeabilización del relleno sanitario, provocando el aumento de aguas ll= uvia durante el escurrimiento del lixiviado  con efecto de dilución (Espinosa= et al., 2010).

 

La relación DBO5/DQO, indicó que la muestra fue muy biodegradable.<= o:p>

 


 

Tabla 1. Caracterización de lixiviados generados en el relleno sanitario Porlón de la ciudad de Riobamba

Parámetros

Unidad

Invierno

Verano

Mínimo

Promedio

Máximo

Desviación

Mínimo

Promedio

Máximo

Desviación

pH

---

8,2

8,3

8,4

0,0817

8,2

8,3

8,4

0,0846

STD

mg/L

5148

5150

5151

1,2645

8099

8100

8104

2,1723

Conductividad=

ms/cm

9.1

9.3

9.5

0,1643

11,8

12,4

13,4

0,6735

Alcalinidad

mg/L

545

550

553

3,3043

298

300

308

4,3541

Turbidez

NTU

1198

1200

1204

2,4837

1815

1820

1825

2,7632

Color

Pt-Co

24048

24050

24053

2,0745

31097

31100

31103

2,4692

DBO5

mg/L

16198

16200

16210

3,986

26998

27000

27002

1,7632

DQO

mg/L

20499

20500

20510

3,8746

26095

26100

26106

4,5823

Tensoactivos<= /o:p>

mg/L

---

---

---

---

2,5

2,7

2,9

0,0173

            Fuente: Elaboración propia.

El color fue uno de los parámetros característico de los lixiviados que en verano resultó ser m= ayor que en invierno, ratificando el efecto de dilución por precipitación, valor= es de color menor a 7000 mg/L en época de lluvia corresponden a un lixiviado v= iejo (Espinosa et al., 2010). La cantidad de dosis óptima para hierro correspondió a la concentración de = 1000 mg/L en que se determinó una menor cantidad de turbidez y una alta remoción= de color  (87,0 %), tal como se indica= en las figuras 1 y 2. Al variar la concentración de peróxido de hidrógeno y concentración constante de sulfato ferroso, se observó que a 400 mg/L de H<= sub>2O2 menos valor de turbidez (90,8 %) y color (86,7 %) presentan las muestras, resultados que se visualizan en las figuras 3 y 4.

            Figura 1. Dosis óptima de Fe2+ al mantener peróxido const= ante

Fuente: Elaboración propia.

 

Tabla 2. Porcentaje de remoción d= e turbiedad y color en el tratamiento Fenton

Dosis H2O2 (mg/L)

Dosis Fe2+ (mg/L)

pH

Turbiedad

Color

NTU

Remoción (%)

Pt-Co

Remoción (%)

400

250

2

1721

5,0

25346

18,0

400

500

2

1667

8,0

24728

20,0

400

1000

2

1540

15,0

23800

23,0

400

1250

2

1644

9,3

23400

24,3

400

250

3

1002

44,5

17456

42,4

400

500

3

814

54,9

12032

60,3

400

1000

3

162

91,0

3940

87,0

400

1250

3

705

60,9

10395

65,7

400

1500

3

830

78,7

13547

55,3

400

250

4

1366

25,0

19127

38,0

400

500

4

1129

38,0

16044

48,0

400

1000

4

1020

44,0

14500

53,0

400

1250

4

1184

35,0

16654

46,0

400

1500

4

1311

28,0

19750

36,0

200

1000

2

1641

4,0

25278

18,1

400

1000

2

1538

10,0

23797

22,8

600

1000

2

1572

8,0

23704

23,2

800

1000

2

1624

5,0

23426

24,1

200

1000

3

609

65,5

15238

48,3

400

1000

3

161

90,8

3920

86,7

600

1000

3

448

74,6

11878

59,7

800

1000

3

557

68,4

16329

44,6

200

1000

4

1315

27,0

18923

38,4

400

1000

4

1012

43,8

14510

52,8

600

1000

4

1225

32,0

15514

49,5

800

1000

4

1441

20,0

18770

38,9

Fuente: Elaboración propia.

Según los datos de la tabla 3 y figura 4 se observó que a pH =3D3 se mantiene la = mejor eficiencia de remoción de turbidez y color, lo que indica que el pH no varí= a al modificar la concentración del reactivo fenton, también se observó que la mezcla de 600 mg/L de peróxido y 1250 mg/L de hie= rro da buenos resultados. Sin embargo  = (Rivas et al., 2004), reporta que la condición óptima de pH es de 3.5, lo que denota la gran dependencia de la composición de lixiviado en estudio. La variación de pH afecta en la velocidad de reacción (Rubio et al., 2014)

Figura 2. Eficiencia en remoción de color con variación de F= e2+

Fuente: Elaboración propia.

Figura 3. Dosis óptima de H2O2 al mantener hierro constante=

Fuente: Elaboración propia.

Figura 4. Eficiencia en remoción de color con variación de = H2O2

Fuente: Elaboración propia.


Tabla 3. Análisis de pH en condiciones distintas del reactivo fenton<= /p>

pH

H2O2
mg/L

Fe2+
mg/L

Turbiedad,
NTU

% Removido Turbiedad

Color
Pt-Co

% Removido color

2

600

1250

1644

10,1

23400

25,1

3

600

1250

170

90,6

4120

85,9

4

600

1250

1200

67,2

10800

65,1

2

400

1000

1540

14,2

23800

23,1

3

400

1000

162

90,9

3940

86,8

4

400

1000

1020

43,7

14500

52,7

Fuente: Elaboración propia.<= /span>

 

Figura 5. Variación de pH a dos reactivos Fenton

 

Fuente: Elaboración propia.

 

Tabla 4. Eficiencia del tratamiento Fenton en eliminación de contaminantes de lixiviados

Parámetros

Unidad

Verano

Invierno

inicial

Final

Eficiencia, %

Inicial

Final

Eficiencia, %

pH

---

8.5

3

---

8.3

3

---

STD

g/L

8.1

2

75,3

5150

1180

77,1

Conductividad=

ms/cm

14.3

4

72,0

9.3

2.6

72,0

Alcalinidad

mg/L

300

200

33,3

550

350

36,4

Turbidez

NTU

1820

162

91,0

1200

150

87,5

Color

pt Co

31100

3940

87,3

24050

3700

84,6

DBO5

mg/L

27000

4050

85,0

16200

2200

86,4

DQO

mg/L

26100

7050

73,0

20500

5350

73,9

Tensoactivos<= /o:p>

mg/L

2.73

1.35

50,5

---

---

---

Fuente: Elaboración propia.

Según los datos de= la tabla 4, el parámetro con mayor eficiencia en la remoción fue la turbidez c= on 91.0 % en verano y 87.5 % en invierno, el color en 87.3 % en verano y 84.6 = % en invierno, la DBO sufrió una reducción de 85 % en época de verano y 86.4 % en invierno, los sólidos totales disueltos también se redujeron en 75.3 %. La = DQO se ha reducido en 73 %. La alcalinidad fue el componente que menor reducción ha sufrido en las dos épocas de análisis 33.3 % a 36.4 %.  Estudios realizados en Huancayo-Perú, indicaron que la eficiencia  a pH c= on un valor de 3.9, sulfato ferroso con 1645,55 mg/L, peróxido de hidrógeno de 10= 96.55 mg/L obtuvo una eficiencia de 42 % en términos de DQO en las dos épocas de estudio (Medina et al., 2012; Medina Valderrama et al., 2018). Estudios realizados en Guanajuato, reportaron eficiencia de 96,88% en turbi= dez y 81.38% en turbidez para una reacción fenton de 1250 mg/L de sulfato ferro= so y 1000 mg/L de peróxido de hidrógeno a pH=3D4 (Huichapa et al., 2003).

Conclusiones.

·       La eficiencia del proceso fenton para tratamiento = de lixiviados se derivó de un adecuado análisis de las condiciones de costo-beneficio soc= ial, económico y ambiental que a través de estrategias metodológicas de trabajo = en campo definieron las condiciones óptimas para alcanzar la condición de bienestar en la comunidad del área de influencia directa. El tratamiento de lixiviados a partir del proceso fenton abarató = costos de producción, fomentó el uso de materiales primarios y renovables resaltan= do las oportunidades de desarrollo local.  

 

·       De acuerdo a los resultados finales se obtuvieron las condiciones óptimas del proceso fenton 400 mg/L de peróxido de hidrógen= o con 1000 mg/L de sulfato de hierro a pH de 3, donde el porcentaje de remoción q= ue se ha logrado para la Demanda Bioquímica de Oxígeno fue de 85,0 % en verano= y 86,4 % en invierno, la Demanda Química de Oxígeno de 73,0 % en invierno y 73,9 %= en verano, la turbidez en 91,0 % en invierno y 87,5 % en verano, la disminució= n de color en 87,3 % para verano y 84,6 % en invierno. Se ha logrado disminuir en 72,0 % la conductividad y en menor porcentaje respecto a la alcalinidad en = 33,3 % en verano y 36,4 % en invierno.

 

 

·       A pesar de que la eficiencia del tratamiento fue alta, no fueron suficientes = sus características para descargar el lixiviado a un cuerpo hídrico, resaltando el hecho de que= se requieren complementariamente otros tipos de tratamientos para el cumplimie= nto de la norma ambiental vigente.

 


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PARA CITAR EL ARTÍCULO INDEXADO.=

 

 

León Chimbolema, J. G., Godoy Ponce, S. C., & Guevara Villegas, M. A. (2020). Eficiencia socio ambiental de la reacción fenton en el tratamiento de lixiviados. Ciencia Digital, 4(3), 271-285. https://doi.org/= 10.33262/cienciadigital.v4i3.1334

 

 



 

 

 

El artículo que se publica es= de exclusiva responsabilidad de los autores y no necesariamente reflejan el pensamiento de la Revista Ciencia Digital.

 

El artículo queda en propiedad de la revista y, por tanto, su publicación parc= ial y/o total en otro medio tiene que ser autorizado por el director de la Revista Ciencia Digital.

 

 

 

 

 



[1] Escue= la Superior Politécnica de Chimborazo, Facultad de Ciencias. Riobamba, Ecuador. gerardo.leon@espoch.edu.ec

[2] Escuela Superior Politécnica de Chimborazo, Facul= tad de Ciencias. Riobamba, Ecuador. sofia.godoy@espoch.edu.ec

[3] Escuela Superior Politécnica de Chimborazo, Facultad de Ciencias. Riobamba, Ecuador. mvillegas@espoch.edu.ec

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                                                 =                                                              = ISSN: 2602-8085

                                                      =                  Vol. 4, N°3, p. 271-285, julio-septiembre, 20 2

 Diseño & Evaluación                                                 =                                         =                             Página 219

 

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